2,2'-Bipyridyl
Catalog Number
ACM366187-1
CAS
366-18-7
IUPAC Name
2-pyridin-2-ylpyridine
Synonyms
2,2'-Dipyridyl, 2,2'-Dipyridine, 2,2'-Bipyridine
Application
Ligand for copper in greener oxidation of alcohols under aerobic conditions.
2,2'-Bipyridyl has been used in the preparation of copper(II)-bipyridine-naringenin complex. It may be used in the preparation of 2,2'-bipyridyl hydrobromide.
Bidentate ligand employed in transition metal catalysis and aluminum initiated polymerization (inorganic syntheses).
Ligand for copper in greener oxidation of alcohols under aerobic conditions.
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air
2,2'-Bipyridyl has been used in the preparation of copper(II)-bipyridine-naringenin complex. It may be used in the preparation of 2,2'-bipyridyl hydrobromide.
Bidentate ligand employed in transition metal catalysis and aluminum initiated polymerization (inorganic syntheses).
Ligand for copper in greener oxidation of alcohols under aerobic conditions.
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air
Molecular Weight
156.18
Molecular Formula
C10H8N2
Product Information
Description
2,2'-Bipyridyl also known as 2,2'-bipyridine, is a symmetrical bipyridine commonly used as a neutral ligand for chelating with metal ions. A study of its impact on Petunia hybrida flowers showed that it caused inhibition of senescence.
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We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Canonical SMILES
c1ccc(nc1)-c2ccccn2
InChI
1S/C10H8N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10/h1-8H
InChI Key
ROFVEXUMMXZLPA-UHFFFAOYSA-N
Boiling Point
273 °C (lit.)
Melting Point
70-73 °C (lit.)
Flash Point
Not applicable
Purity
0.99
Solubility
0.04 M;Very sol in alcohol, ether, and benzene;Soluble in oxygenated solvents;In water, 5.93X10+3 mg/l @ 25 °C;Solubility in water, g/100ml: 6.4
Appearance
White to Almost white powder to crystal
Storage
Store under inert gas
Complexity
120
Condition to avoid
Light Sensitive
Exact Mass
156.068748g/mol
Hazard Statements
H301 : Toxic if swallowed.H315 : Causes skin irritation.H319 : Causes serious eye irritation.H341 : Suspected of causing genetic defects.
Heavy Atom Count
12
MDL Number
MFCD00006212
Monoisotopic Mass
156.068748g/mol
Precautionary Statements
P501 : Dispose of contents/ container to an approved waste disposal plant.P270 : Do not eat, drink or smoke when using this product.P202 : Do not handle until all safety precautions have been read and understood.P201 : Obtain special instructions before use.P264 : Wash skin thoroughly after handling.P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.P308 + P313 : IF exposed or concerned: Get medical advice/ attention.P337 + P313 : If eye irritation persists: Get medical advice/ attention.P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.P332 + P313 : If skin irritation occurs: Get medical advice/ attention.P362 : Take off contaminated clothing and wash before reuse.P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth.P405 : Store locked up.
Reaxys Registry Number
113089
Refractive Index
1.62
Rotatable Bond Count
1
Signal Word
Danger
Specific Gravity
1.16
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