Spiro[9H-fluorene-9,9'-[9H]xanthene]-2,2',7,7'-tetramine
Catalog Number
ACM1887794220-2
CAS
1887794-22-0
Synonyms
N2,N2,N7,N7,N2',N2',N7',N7'-octakis(4-methoxyphenyl)spiro[9H-fluorene-9,9'-[9H]xanthene]-2,2',7,7'-tetramine, X60
Application
X60 can be used as a conducting polymer in the formation of perovskite based solar cells with high efficiency.
Molecular Weight
1241.43
Molecular Formula
C81H68N4O9
Product Information
Description
Spiro[9H-fluorene-9,9'-[9H]xanthene]-2,2',7,7'-tetramine (X60) is a hole transporting material (HTM) with a nonplanar 3D structure which reduces the electronic coupling and charge recombination. It can be used as a starting material in the fabrication of green and cost effective p-type organic semiconductors.
X60 is cheaper alternative to Spiro-OMeTAD.
X60 is a spiro[fluorene-9,9'-xanthene] (SFX) based organic hole transport material (HTM).
Devices with X60 as HTM showed high power conversion efficiencies (PCEs) amounting to 7.30% in solid-state dye-sensitized solar cells (ssDSCs) and 19.84% in perovskite solar cells (PSCs). These results are competitive with the reported record PCEs of ssDSC and PSC devices based on the well-known HTM Spiro-OMeTAD. In addition, almost no hysteretic behavior could be observed in the X60-based PSCs, and the photovoltaic parameters of the devices are not affected by the scan rates used.
X60 is cheaper alternative to Spiro-OMeTAD.
X60 is a spiro[fluorene-9,9'-xanthene] (SFX) based organic hole transport material (HTM).
Devices with X60 as HTM showed high power conversion efficiencies (PCEs) amounting to 7.30% in solid-state dye-sensitized solar cells (ssDSCs) and 19.84% in perovskite solar cells (PSCs). These results are competitive with the reported record PCEs of ssDSC and PSC devices based on the well-known HTM Spiro-OMeTAD. In addition, almost no hysteretic behavior could be observed in the X60-based PSCs, and the photovoltaic parameters of the devices are not affected by the scan rates used.
Canonical SMILES
COC1=CC=C(C=C1)N(C2=CC=C(OC)C=C2)C3=CC=C4C(C5(C6=CC(N(C7=CC=C(OC)C=C7)C8=CC=C(OC)C=C8)=CC=C6OC9=CC=C(N(C%10=CC=C(OC)C=C%10)C%11=CC=C(OC)C=C%11)C=C59)C%12=CC(N(C%13=CC=C(OC)C=C%13)C%14=CC=C(OC)C=C%14)=CC=C4%12)=C3
Inchi
1S/2C11H9N5.C2F6NO4S2.Co/c2*1-4-10(15-8-2-6-12-15)14-11(5-1)16-9-3-7-13-16;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h2*1-9H;;/q;;-1;+3
InChIKey
ZURJMCGADUHLSF-UHFFFAOYSA-N
Boiling Point
232 °C (lit.)
Melting Point
247 °C
Flash Point
Not applicable
Appearance
beige; solid
storage
2-8°C
MDL Number
MFCD12022511
Refractive Index
n20/D 1.464 (lit.)
Solubility In Water
insoluble (Methanol and Hexane)
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